"NAFION"FILMS CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification Tradenames and Synonyms Company Identification
"NAFION" is a registered trademark of DuPont.
"NAFION"117, 120
"NAFION" NE105, NE105F, NE1135, NE115N, NE151F,
"NAFION" NE1035, NF1035N,
"NAFION" NE112, NF115,
"NAFION" NX112F, NX115F, NX117F
Manufacturer/Supplier:
Fuel Cell Scientific LLC.
12 Waterhouse Rd.
Stoneham, MA 02180
Emergency Phone: (617) 629-7474
CHEMTREC: (800) 424-9300
Web Site: www.fuelcellscientific.com
Product Information 1-(800) 441-7515
Transport Emergency 1-(800) 424-9300
Medical Emergency 1-(800) 441-3637
COMPOSITION/ INFORMATION ON INGREDIENTS
Components
| Material | CAS Number | % |
| TETRAFLUOROETHYLENE/PERFLUORO (4-METHYL-3, 6-DIOXA-7-OCTENE-1-SULFONIC ACID) CO POLYMER or |
31175-20-9 | 100 |
| TETRAFLUOROETHYLENE/PERFLUORO (4-METHYL-3, 6-DIOXA-7-OCTENE-1-SULFONYL FLUORIDE) COPOLYMER or |
26654-97-7 | 100 |
| Sodium Salts of above |
Components (Remarks)
Material is not known to contain Toxic Chemicals under Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372.
HAZARDS IDENTIFICATION
Potential Health Effects
ADDITIONAL HEALTH EFFECTS
Read "Safety on Handling and Use" Bulletin E63118 before using "Nafion."
ACUTE OR IMMEDIATE EFFECTS: ROUTES OF ENTRY AND SYMPTOMS
INGESTION: Not a probable route of exposure
SKIN: Prolonged contact may cause skin irritation to some individuals.
EYE: Reversible cornea opacity and mild conjunctivitis.
INHALATION: Not respirable in pellet form. Inhalation of fumes from overheating or burning "Nafion," or from smoking tobacco or cigarettes contaminated with polymer dust, may cause polymer fume fever, a flu-like illness with chills and fever. Symptoms may not occur for several hours after exposure and go away in 24-48 hours even in absence of treatment.
Carcinogenicity Information
None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSGA, or ACGIH as a carcinogen.
FIRST AID MEASURES
First Aid
INHALATION
If exposed to fumes from overheating or combustion, remove to fresh air.
SKIN CONTACT
The compound is not likely to be hazardous by skin contact but cleansing the skin after use is advisable.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician.
INGESTION
No specific intervention is indicated as compound is not likely to be hazardous by ingestion. Consult a physician if necessary.
FIRE FIGHTING MEASURES
Flammable Properties
Flash Point: N/A
Method: N/AHazardous gases/vapors produced in fire are hydrogen fluoride (HF), and, organic fluorine compounds.
Extinguishing Media
Water, Foam, Dry Chemical, CO2
Fire Fighting Instructions
Wear protective clothing and use self-contained breathing equipment to protect from acidic fluoride fumes.
ACCIDENTAL RELEASE MEASURES
Safeguards (Personnel)
Note: Review the FIREFIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with cleanup. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during cleanup.
Accidental Release Measures
Pick up to avoid slipping hazard.
HANDLING AND STORAGE
Handling
See FIRST AID and PERSONAL PROTECTIVE EQUIPMENT Sections.
Storage
Store in cool, dry place. Keep away from flammable materials.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls
VENTILATION: Local exhaust for operations above 150 C (302 F)
Personal Protective Equipment
EYE/FACE PROTECTION
Wear safety glasses.
Recommended glove material: No information was found for selection of materials of construction for protective clothing.RESPIRATOR Use a NIOSH approved positive pressure air supplied respirator if concentrations may exceed exposure limits. Air purifying respirators are inadequate for this material.
Exposure guidelines
Exposure Limits
"NAFION"FILMS
| PEL | (OSHA) | Particulates (Not Otherwise Regulated) 15 mg/m3, 8 Hr. TWA, total dust 5 mg/m3, 8 Hr. TWA, respirable dust |
PHYSICAL AND CHEMICAL PROPERTIES
Physical Data
| % Volatiles | none |
| Solubility in Water | Insoluble |
| Odor | None |
| Form | Membrane |
| Color | Natural |
STABILITY AND REACTIVITY
Chemical Stability
Stable at normal temperatures and storage conditions.
Conditions to Avoid
At temperatures above 150 C (302 F), toxic and corrosive decomposition fumes are liberated.
Incompatibility with other materials
None reasonably foreseeable.
Decomposition
HAZARDOUS DECOMPOSITION PRODUCTS- hydrogen fluoride, carbonyl fluoride, toxic fluoro-organic compounds.
ECOLOGICAL INFORMATION
Ecotoxicological Information
AQUATIC TOXICITY:
No information is available. Toxicity is expected to be low based or insolubility in water.
DISPOSAL CONSIDERATIONS Waste Disposal Preferred options for disposal are (1) recycling and (2) landfill. Incinerate only if incinerator is capable of scrubbing out hydrogen fluoride and other acidic combustion products. Treatment, storage, transportation, and disposal must be in accordance with applicable federal, state/provincial, and local regulations. TRANSPORTATION INFORMATION Shipping Information DOT
Not regulated.
REGULATORY INFORMATION
U.S. Federal Regulations
TSCA Inventory Status: In compliance with TSCA Inventory requirements for commercial purposes.
State Regulations (US)
STATE RIGHT-TO-KNOW LAWS
No substances on the state hazardous substances list, for the states indicated below, are used in the manufacture of the products on this Material Safety Data Sheet.
SUBSTANCES ON THE PENNSYLVANIA HAZARDOUS SUBSTANCES LIST PRESENT AT A CONCENTRATION OF 1% OR MORE (0.01% FOR SPECIAL HAZARDOUS SUBSTANCES): None known
WARNING: SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: None known.
SUBSTANCES ON THE NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE LIST PRESENT AT A CONCENTRATION OF 1% OR MORE (0.1% FOR SUBSTANCES IDENTIFIED AS CARCINOGENS, MUTAGENS OR TERATOGENS): None known.
OTHER INFORMATION
Additional information
MEDICAL USE: CAUTION: Do not use in medical applications involving permanent implantation in the human body. For other medial applications see DuPont Bulletin No. H-50102.
The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsibility for MSDS:L.W. Buxton Telephone:
Manufacturer Address:
DuPont Fluropolymers
Chesnut Run Plaza 713
Wilmington, DE 19880-0713
(302) 999-4658
Distributor Address:
Fuel Cell Scientific
12 Waterhouse Rd.
Stoneham, MA 02180
Telephone:
(617) 629-7474
Fax:
(617) 629-7373


